Abstract
Current interest in divalent calcium-based gel polymer electrolyte systems was rapid growth because of their potential in developing high-energy storage devices such as supercapacitors. However, research in calcium-based electrolytes was still poorly understood regarding the poor ionic conductivity, high crystalline structure and low electrochemical potential because of the obstacles in finding suitable electrolytes incorporate with the calcium salts. Therefore, this thesis focuses on the preparation and characterization of calcium thiocyanate (CaSCN) and calcium nitrate (Ca(N03)2) based gel polymer electrolytes. The research included two stages of work where at stage one various salt concentrations from 0 wt.% to 45 wt.% of CaSCN and Ca(N03)2 salts were added with 0.5 g of agarose polymer matrix and dissolved in 20 ml of DMSO, they were stirred for several days until a clear solution formed. Then, to produce a free-standing film, they were cast by solution casting method and heated in the oven at the temperature of-80 ° C. They were characterized using Electrical Impedance Spectroscopy (EIS) to examine their conductivity studies, structural analysis by X-Ray Diffraction Spectroscopy (XRD), and Fourier Transform Infrared Spectroscopy. Voltage potential characterization by Linear Sweep Voltammetry (LSV) and Cyclic Voltammetry (CV).
Metadata
Item Type: | Thesis (Masters) |
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Creators: | Creators Email / ID Num. Mohd Rafi, Noraishah Syuhada 2020159939 |
Contributors: | Contribution Name Email / ID Num. Thesis advisor Zainal Abidin, Siti Zafirah UNSPECIFIED |
Subjects: | Q Science > QD Chemistry Q Science > QD Chemistry > Analytical chemistry > Quantitative analysis > Electrochemical analysis |
Divisions: | Universiti Teknologi MARA, Shah Alam > Faculty of Applied Sciences |
Programme: | Master of Science (Physics) |
Keywords: | Liquid electrolytes, polymer electrolytes, calcium-based electrolytes |
Date: | 2023 |
URI: | https://ir.uitm.edu.my/id/eprint/91040 |
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