Sorption of Amido Black 10 B onto calcined Zn-Al-NO₃ layered double hydroxide and calcined Zn-Al-CO₃ layered double hydroxide / Mohd Hanisafwan Suhaimi

Suhaimi, Mohd Hanisafwan (2009) Sorption of Amido Black 10 B onto calcined Zn-Al-NO₃ layered double hydroxide and calcined Zn-Al-CO₃ layered double hydroxide / Mohd Hanisafwan Suhaimi. Student Project. Faculty of Applied Sciences, Shah Alam. (Unpublished)

Abstract

Layered double hydroxides (LDHs) calcined, denoted as CLDHs, have been shown to recover their original layered structure in the presence of appropriate anions. In the light of this so-called "memory effect", the removal of Amido Black (AB), an anionic dye, from aqueous solution by calcined Zn-Al-NO₃ and Zn-Al-C0₃ LDHs was investigated in batch mode. The study looked at the influence of pH values, dye-adsorbent contact time, initial dye concentration, adsorbent dosage, particle size, and various temperatures on the decolorization rate of AB. The adsorption isotherms, described by Freundlich model are L-type. The characterization of the solids CLDHs, both before and after removal of AB, by X-ray diffraction, Scanning Electron Microscope and infrared spectroscopy shows that the AB adsorption on CLDHs is enhanced by reconstruction of a matrix hydrotalcite intercaled by the dye, and the intercalation of the organic ion was clearly evidenced by the net increase in the basal spacing from 7.6 A for Zn-Al-NO₃ and 7.59 for Zn-Al-CO₃.

Download

[img] Text
PPb_MOHD HANISAFWAN SUHAIMI AS 09_5.pdf

Download (5MB)

Metadata

Item Type: Monograph (Student Project)
Creators:
CreatorsID Num.
Suhaimi, Mohd HanisafwanUNSPECIFIED
Subjects: Q Science > QD Chemistry > Organic chemistry
Q Science > QD Chemistry > Physical and theoretical chemistry
Divisions: Faculty of Applied Sciences
Item ID: 23098
Uncontrolled Keywords: double hydroxide
URI: http://ir.uitm.edu.my/id/eprint/23098

Actions (login required)

View Item View Item

Downloads

Downloads per month over past year