Ionic conductivity studies on magnesium-based cellulose acetate polymer gel electrolytes / Aniza Omar … [et al.]

Omar, Aniza and Zainal Abidin, Siti Zafirah and Kamisan, Ainnur Sherene and Saaid, Siti Irma Yuana and Ali, Ab Malik Marwan and Yahya, Muhd Zu Azhan (2015) Ionic conductivity studies on magnesium-based cellulose acetate polymer gel electrolytes / Aniza Omar … [et al.]. Scientific Research Journal, 12 (2). pp. 26-34. ISSN 1675-7009

Abstract

Magnesium-based polymer gel electrolytes consist of magnesium triflate (MgTf) salt, a mixture of ethylene carbonate (EC) and diethyl carbonate (DEC) solvents as well as cellulose acetate as a polymeric agent were prepared via direct dissolution method. The highest ionic conductivity obtained for MgTf-EC:DEC(l: 1) liquid electrolytes was 2.66 x 10~3 S cm1 and enhanced to 2.73 x 10~3 S cm1 with the addition of cellulose acetate. These results were in agreement with the activation energy obtained with the lowest value of 0.11. The best explanation on the enhancement in ionic conductivity ofPGE is due to the "breathingpolymeric chain model". The plots of conductivity-temperature were shown to obey an Arrhenius rule. The electrical properties of the sample with the highest conductivity were analyzed using electrical permittivity-based frequency and temperature dependence in the range of 100Hz- 1 MHz and303-373K, respectively. The variation in dielectric permittivity (er ande) as a function of frequency at different temperatures exhibited decays at higher frequencies and a dispersive behavior at low frequencies. Based on the observed electrical properties, it can be inferred that this polymer gel electrolyte could be a promising candidate as an electrolyte in electrochemical devices.

Metadata

Item Type: Article
Creators:
CreatorsID Num. / Email
Omar, AnizaUNSPECIFIED
Zainal Abidin, Siti ZafirahUNSPECIFIED
Kamisan, Ainnur ShereneUNSPECIFIED
Saaid, Siti Irma YuanaUNSPECIFIED
Ali, Ab Malik MarwanUNSPECIFIED
Yahya, Muhd Zu AzhanUNSPECIFIED
Subjects: Q Science > QD Chemistry > Organic chemistry > Polymers. Macromolecules
Divisions: Universiti Teknologi MARA, Shah Alam > Research Management Centre (RMC)
Journal or Publication Title: Scientific Research Journal
Journal: UiTM Journal > Scientific Research Journal
ISSN: 1675-7009
Volume: 12
Number: 2
Page Range: pp. 26-34
Item ID: 16081
Uncontrolled Keywords: Magnesium triflate; cellulose acetate; ionic conductivity; polymer gel electrolyte; electrical properties component
URI: http://ir.uitm.edu.my/id/eprint/16081

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