Ultrasonic velocity and elastic anomaly in charge-ordered Nd₀.₅Ca₀.₅Mn₁₋ₓCrₓO₃, Nd₀.₃La₀.₂Ca₀.₅₋ᵧSrᵧMnO₃ and Dy₀.₅₋zErzBa₀.₅CoO₃ magnetic ceramics / Suhadir Shamsuddin

Shamsuddin, Suhadir (2015) Ultrasonic velocity and elastic anomaly in charge-ordered Nd₀.₅Ca₀.₅Mn₁₋ₓCrₓO₃, Nd₀.₃La₀.₂Ca₀.₅₋ᵧSrᵧMnO₃ and Dy₀.₅₋zErzBa₀.₅CoO₃ magnetic ceramics / Suhadir Shamsuddin. In: The Doctoral Research Abstracts. IGS Biannual Publication, 7 (7). Institute of Graduate Studies, UiTM, Shah Alam.

Abstract

Three series of charge-ordered compounds Nd0.5Ca0.5Mn1-xCrxO3 (NCMCO) (0≤x≤0.05), Nd₀.₃La₀.₂Ca₀.₅₋ᵧSrᵧMnO₃ (NLCSMO) (0≤y≤0.05) and Dy₀.₅₋zErzBa₀.₅CoO₃ (DEBCO) (0≤z≤0.05) ceramics were prepared using the solid-state reaction method. For NCMCO series, resistivity and susceptibility measurements for the x=0 sample showed an insulating behavior and an anti-ferromagnetic (AFM) transition at 230 K as well as a charge-ordering (CO) transition at 280 K. The substitution of Cr induces a ferromagnetic-paramagnetic (FM-PM) and metal-insulator (MI) transition as well as gradually suppressing the CO state due to weakening of the Jahn-Teller (JT) effect. Quenching to reduce the oxygen content of the x=0.05 sample caused the MI transition temperature to shift to lower temperatures most likely due to oxygen reduction. On the other hand, both longitudinal and shear velocities at 100 K increased significantly with Cr substitution indicating improvement in elastic properties. However, quenching of the x=0.05 sample slightly decreased both velocities and related elastic moduli…

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Item Type: Book Section
Creators:
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Shamsuddin, Suhadir
UNSPECIFIED
Subjects: L Education > LB Theory and practice of education > Higher Education > Dissertations, Academic. Preparation of theses > Malaysia
Divisions: Universiti Teknologi MARA, Shah Alam > Institut Pengajian Siswazah (IPSis) : Institute of Graduate Studies (IGS)
Series Name: IGS Biannual Publication
Volume: 7
Number: 7
Keywords: Abstract; Abstract of thesis; Newsletter; Research information; Doctoral graduates; IPSis; IGS; UiTM; Ultrasonic velocity
Date: 2015
URI: https://ir.uitm.edu.my/id/eprint/19391
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