Dielectric behaviours of peo-licf 3 so 3 electrolytes / Siti Zaubidah Abdullah

Siti Zaubidah, Abdullah (2013) Dielectric behaviours of peo-licf 3 so 3 electrolytes / Siti Zaubidah Abdullah. Journal of Academia, 3 (1). pp. 77-82. ISSN 2289-6368

Abstract

Polymer electrolyte composed of poly (ethylene oxide) as a host polymer and LiCF 3 SO 3 as salt was studied. Different compositions of PEO-LiCF 3 SO 3 electrolytes were prepared by solution casting technique. Measurement of conductivity and dielectric properties were carried out on these films as a function of frequency at various temperatures. The highest conductivity obtained was 7.75 x 10 -8 S/cm for a ratio of 80 wt% PEO: 20 wt% LiCF 3 SO 3 . The relaxation time, τ for the ionic charge carriers, was obtained from the variation of loss tangent (tan δ) with frequency for the highest conductivity value. The linear behavior of temperature dependence of the complex film appears to obey the Arrhenius Law. The activation energy for the highest conductivity PEO-LiCF 3 SO 3 sample was found 0.74 eV.

Metadata

Item Type: Article
Creators:
CreatorsID Num. / Email
Siti Zaubidah, Abdullahzaubidah@ns.uitm.edu.my
Subjects: Q Science > QC Physics > Electricity and magnetism > Dielectrics
T Technology > TK Electrical engineering. Electronics. Nuclear engineering > Electric apparatus and materials. Electric circuits. Electric networks
Divisions: Universiti Teknologi MARA, Negeri Sembilan > Kuala Pilah Campus > Faculty of Applied Sciences
Journal or Publication Title: Journal of Academia
Journal: UiTM Journal > Journal of Academia UiTM Negeri Sembilan
ISSN: 2289-6368
Volume: 3
Number: 1
Page Range: pp. 77-82
Official URL: https://nsembilan.uitm.edu.my/joacns
Item ID: 29252
Uncontrolled Keywords: poly (ethylene oxide), LiCF3SO3, conductivity, relaxation time, dielectric
URI: http://ir.uitm.edu.my/id/eprint/29252

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