Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad

Ahmad, Illuni Hayaty (2009) Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad. [Student Project] (Unpublished)

Abstract

Three Schiff base ligands were suscesssfully synthesized by condensation reaction of 4-hydroxybenzaldehye with benzylamine, o-phenylenediamine and ethylenediamine in 1:1 and 2:1 ratio yielding 4-hbba, 4-hbopd and 4-hben, respectively. Metal complex of Cu(II) has been isolated with the 4-hbba ligand and all of the synthesized compounds are characterized by infrared spectroscopy, ¹H NMR, magnetic susceptibility and molar conductivity. It is proposed that the synthesized complex [Cu(4-hbba)(OAc)₂]₂.xH₂O, has a tetrahedral geometry. The synthesized compounds have been screened for antioxidant properties by comparing their activities with vitamin C, where the ligands 4-hben and 4-hbopd are found to possess some antioxidation activities.

Metadata

Item Type: Student Project
Creators:
CreatorsID Num. / Email
Ahmad, Illuni HayatyUNSPECIFIED
Subjects: Q Science > QD Chemistry > Organic chemistry
Divisions: Universiti Teknologi MARA, Shah Alam > Faculty of Applied Sciences
Item ID: 23249
Uncontrolled Keywords: schiff base; 4-hydroxybenzaldehyde
URI: http://ir.uitm.edu.my/id/eprint/23249

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