Synthesis and physicochemical analysis of Polystyrene-Anchored Pd(II) metal complex / Siti Kamilah Che Soh, Siti Aminah Jusoh and Mustaffa Shamsuddin

Che Soh, Siti Kamilah and Jusoh, Siti Aminah and Shamsuddin, Mustaffa (2014) Synthesis and physicochemical analysis of Polystyrene-Anchored Pd(II) metal complex / Siti Kamilah Che Soh, Siti Aminah Jusoh and Mustaffa Shamsuddin. Scientific Research Journal, 11 (2). pp. 1-10. ISSN 1675-7009

Official URL: https://srj.uitm.edu.my/

Abstract

A polystyrene (PS)-anchored Pd(II) metal complex was synthesized on cross-linked polymer by heating a mixture of chlorometylated polystyrene with phenyldithiocarbazate and carbon disulfide in the presence of potassium hydroxide (KOH) in dimethylformamide (DMF). The reaction mixture was heated at 80 °C to form the corresponding phenyldithiocarbazate-functionalized polymer. Then, it was treated with bis(benzonitrile)palladium(II) chloride. The
properties of dark colored polymer, impregnated with the metal complex was then characterized by various spectroscopic technique such as Fourier Transform Infrared (FTIR), Scanning Electron Microscopy/Energy Dispersive X-ray (SEM/EDX), CHNS elemental analysis, BET surface area, X-ray Diffraction (XRD), Thermogravimetric (TGA) and Inductively Coupled Plasma-Optical Emission (ICP-OES) spectroscopy.

Metadata

Item Type: Article
Creators:
Creators
Email / ID Num.
Che Soh, Siti Kamilah
sitikamilah@umt.edu.my
Jusoh, Siti Aminah
UNSPECIFIED
Shamsuddin, Mustaffa
UNSPECIFIED
Subjects: Q Science > QD Chemistry > Inorganic chemistry > Palladium
T Technology > TP Chemical technology > Polystyrene
Divisions: Universiti Teknologi MARA, Shah Alam > Research Management Centre (RMC)
Journal or Publication Title: Scientific Research Journal
UiTM Journal Collections: UiTM Journal > Scientific Research Journal (SRJ)
ISSN: 1675-7009
Volume: 11
Number: 2
Page Range: pp. 1-10
Keywords: Polystyrene; Palladium; Catalyst
Date: 2014
URI: https://ir.uitm.edu.my/id/eprint/12430
Edit Item
Edit Item

Download

[thumbnail of AJ_SITI KAMILAH CHE SOH SRJ 14 1.pdf] Text
AJ_SITI KAMILAH CHE SOH SRJ 14 1.pdf

Download (439kB)

ID Number

12430

Indexing

Statistic

Statistic details